956469-82-2Relevant articles and documents
Palladium(II)-catalyzed rearrangement of glycal trichloroacetimidates: Application to the stereoselective synthesis of glycosyl ureas
Mercer, Gregory J.,Yang, Jaemoon,McKay, Matthew J.,Nguyen, Hien M.
supporting information; experimental part, p. 11210 - 11218 (2009/02/05)
The research on the area of glycosyl urea derivatives, in which the O- and N-glycosidic bonds are replaced with the urea-glycosidic linkages, has recently emerged with applications in the field of aminoglycoside antibiotics. We have developed a novel meth
Palladium-catalyzed glycal imidate rearrangement: Formation of α- and β-N-glycosyl trichloroacetamides
Yang, Jaemoon,Mercer, Gregory J.,Nguyen, Hien M.
, p. 4231 - 4234 (2008/02/14)
A novel palladium(ll)-catalyzed stereoselective synthesis of α- aα (v-glycosyl trichloroacetamldes has been developed. The α - and β-selectivity at the anomeric carbon depends on the nature of the palladium-ligand catalyst. While the cationic palladium(ll
