956472-47-2Relevant academic research and scientific papers
Regioselective platinum catalyzed β-hydrosilylation of allylic benzene derivatives with cyclic siloxane d4H
El Malki, Abdelghani,Hannioui, Abdellah,El Mostapha, Rakib,Knouzi, Nourredine,Vaultier, Michel
experimental part, p. 361 - 363 (2012/05/31)
Conditions have been found for an efficient regioselective β-hydrosilylation of allylbenzene, 2-allyl-1-trimethylsiloxybenzene, 4-allyl-1,2-(methylenedioxy)benzene, allylpentafluorobenzene, and 4-allyl-2-methoxy-1-trimethylsiloxybenzene with D4H in the presence of Karstedt's-catalyst or platinum black under mild conditions leading quantitatively to functionalized tetramethylcyclosiloxanes 3.
