956480-08-3Relevant academic research and scientific papers
Palladium-catalyzed asymmetric allylic alkylation of indoles by C-N bond axially chiral phosphine ligands
Mino, Takashi,Ishikawa, Miho,Nishikawa, Kenji,Wakui, Kazuya,Sakamoto, Masami
, p. 499 - 504 (2013)
Abstract The palladium-catalyzed asymmetric allylic alkylation of indoles with 1,3-diphenyl-2-propenyl acetate using P/N-type ligands such as N-aryl indole, C-N bond axially chiral aminophosphine (aS)-L4, gave the desired products 1 in good yields and wit
Highly enantioselective Pd-catalyzed allylic alkylation of indoles using sulfur-MOP ligand
Hoshi, Takashi,Sasaki, Koji,Sato, Shun,Ishii, Yuichi,Suzuki, Toshio,Hagiwara, Hisahiro
supporting information; experimental part, p. 932 - 935 (2011/04/22)
The preparation of various (R)-Sulfur-MOP ligands with aryl and alkyl substituents on sulfur, and the application of these ligands to Pd-catalyzed asymmetric allylic alkylation of indoles is reported. The sulfur substituent served as an effective stereoco
