956480-16-3Relevant academic research and scientific papers
Highly enantioselective Pd-catalyzed allylic alkylation of indoles using sulfur-MOP ligand
Hoshi, Takashi,Sasaki, Koji,Sato, Shun,Ishii, Yuichi,Suzuki, Toshio,Hagiwara, Hisahiro
, p. 932 - 935 (2011)
The preparation of various (R)-Sulfur-MOP ligands with aryl and alkyl substituents on sulfur, and the application of these ligands to Pd-catalyzed asymmetric allylic alkylation of indoles is reported. The sulfur substituent served as an effective stereoco
Spiro indane-based phosphine-oxazolines as highly efficient P,N ligands for enantioselective Pd-catalyzed allylic alkylation of indoles and allylic etherification
Qiu, Zhongxuan,Sun, Rui,Yang, Kun,Teng, Dawei
, (2019/05/01)
A series of indane-based phosphine-oxazoline ligands with a spirocarbon stereogenic center were examined for palladium-catalyzed asymmetric allylic alkylation of indoles. Under optimized conditions, high yields (up to 98%) and enantioselectivities (up to
