956730-50-0Relevant academic research and scientific papers
Group 14 metal terminal phosphides: Correlating structure with |J MP|
Tam, Eric C. Y.,Maynard, Nicola A.,Apperley, David C.,Smith, J. David,Coles, Martyn P.,Fulton, J. Robin
, p. 9403 - 9415 (2012/11/07)
A series of heavier group 14 element, terminal phosphide complexes, M(BDI)(PR2) (M = Ge, Sn, Pb; BDI = CH{(CH3)CN-2,6-iPr 2C6H3}2; R = Ph, Cy, SiMe 3) have been synthesized. Two
A new type of heteroleptic complex of divalent lead and synthesis of the P-plumbyleniophosphasilene, R2Si=P-Pb(L): (L = β-diketiminate)
Yao, Shenglai,Block, Stefan,Brym, Markus,Driess, Matthias
, p. 3844 - 3846 (2008/03/13)
The synthesis and structures of the first heteroleptic β-diketiminato complexes of lead(ii) with terminal phenolato, bis(trimethylsilyl)amido, bis(trimethylsilyl)phosphanido and silylidenephosphanido ligands are reported; 207Pb NMR spectroscopic data indicate that lead(ii) can serve as a σ-donor or acceptor centre, depending on the electronegativity of the terminal ligand. The Royal Society of Chemistry.
