95677-63-7Relevant academic research and scientific papers
Steroids. Part 21. Photorearrangement of Steroidal Nitronate Salts and a N-Butyl Spiro-oxaziridine
Edge, Graham J.,Imam, Syed H.,Marples, Brian A.
, p. 2319 - 2326 (2007/10/02)
Irradiation, at 254 nm, of ethanol solutions of nitro-steroids in the presence of an excess of sodium ethoxide gave a range of products including hydroxamic acids, ketones, and alkenes possibly derived from the anions of the N-hydroxyoxaziridines.Alternatively, the ketones and hydroxamic acids may be derived from the anions of the hydroxy-nitroso compounds.The proportions of products depend on the ring size and stereochemistry and the photoreactions differ significantly from those observed for N-alkyl spiro-oxaziridines including a steroidal N-butyl spiro-oxaziridine.
