956972-09-1Relevant academic research and scientific papers
A Facile Synthesis of Robinson's NHC-Stabilised Diborane(4)
Trose, Michael,Cordes, David B.,Slawin, Alexandra M. Z.,Stasch, Andreas
, p. 3811 - 3814 (2020)
Reactions of bis(pinacolato)diboron (B2pin2) with [(IDip)AlH3] {IDip = (HCNDip)2C:, Dip = 2,6-iPr2C6H3} afforded both the new diborane [(IDip)BH2B(pin)] and the known compound [(IDip)BH2BH2(IDip)] in a facile one-pot procedure; the latter reaction is improved by the addition of free IDip. [(IDip)AlH3] transfers both IDip and hydride ligands to the diborane moiety in a halide-free approach. [(IDip)BH2B(pin)] was structurally and spectroscopically characterised and additional spectroscopic data for [(IDip)BH2BH2(IDip)] is reported.
Synthesis and Stabilization of Neutral Compounds with Homonuclear Bonds
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Page/Page column 7, (2010/03/04)
The present invention is directed to the synthesis and stabilization of neutral molecules containing homonuclear single or multiple bonds, methods of preparation, and uses thereof.
EPR studies of the generation, structure, and reactivity of n-heterocyclic carbene borane radicals
Walton, John C.,Brahmi, Malika Makhlouf,Fensterbank, Louis,Lacote, Emmanuel,Malacria, Max,Chu, Qianli,Ueng, Shau-Hua,Solovyev, Andrey,Curran, Dennis P.
, p. 2350 - 2358 (2010/04/30)
N-Heterocyclic carbene boranes (NHC-boranes) are a new "clean" class of reagents suitable for reductive radical chain transformations. Their structures are well suited for their reactivity to be tuned by inclusion of different NHC ring units and by approp
A stable neutral diborene containing a B=B double bond
Wang, Yuzhong,Quillian, Brandon,Wei, Pingrong,Wannere, Chaitanya S.,Xie, Yaoming,King, R. Bruce,Schaefer III, Henry F.,Schleyer, Paul V. R.,Robinson, Gregory H.
, p. 12412 - 12413 (2008/04/04)
The syntheses and molecular structures of four compounds are reported: 1 (RBBr3), 2 (R(H)2B-B(H)2R), 3 (R(H)B=B(H)R), and 4 (RBH3) (R = :C{N(2,6-Pri2C6H3)CH}2/su
