95718-87-9Relevant academic research and scientific papers
Switchable self-assembly of a bioinspired alkyl catechol at a solid/liquid interface: Competitive interfacial, noncovalent, and solvent interactions
Saiz-Poseu, Javier,Faraudo, Jordi,Figueras, Antoni,Alibes, Ramon,Busque, Felix,Ruiz-Molina, Daniel
experimental part, p. 3056 - 3063 (2012/04/23)
The large tendency of catechol rings to adsorb on surfaces has been studied by STM experiments with molecular resolution combined with molecular-dynamics simulations. The strong adhesion is due to interactions with the surface and solvent effects. Moreove
Synthesis and structure-activity relationships of phaffiaol and related antioxidants
Jinno, Shuji,Okita, Takaaki
, p. 1688 - 1694 (2007/10/03)
Total synthesis of a novel long chain alkyl phenol, phaffiaol (1), a potent antioxidant isolated from Phaffia rhodozyma, was achieved via three reaction steps starting from 3,5-dibromosalicylaldehyde (2). We also prepared several types of long chain alkyl
Novel cytotoxic, alkylated hydroquinones from Lannea welwitschii
Groweiss, Amiram,Cardellina II, John H.,Pannell, Lewis K.,Uyakul, Duangchan,Kashman, Yoel,Boyd, Michael R.
, p. 116 - 121 (2007/10/03)
Two novel natural products, lanneaquinol (1) and 2'(R)- hydroxylanneaquinol (2), were isolated from the organic extract of the plant Lannea welwitschii (Hiern) Engl. Their structures were solved by spectroanalytical methods and confirmed by comparison to
Synthesis and Identification of ω-Phenylalkylcatechols in Burmese Lac
Jefferson, Alan,Sargent, Melvyn V.,Wangchareontrakul, Sirichai
, p. 19 - 25 (2007/10/02)
The presence of 3-(10'-phenyldecyl)- (2) (2percent), 3-(12'-phenyldodecyl)- (3) (6percent), 4-(10'-phenyldecyl)- (4) (0.3percent) and 4-(12'-phenyldodecyl)-benzene-1,2-diol (5) (0.3percent) in Burmese lac, the sap of Melanorrhoea usitata Wall has been confirmed by the synthesis of these compounds and a comparison of the gas chromatographic retention times and the mass spectral characteristic of their bis-O-(trimethylsilyl) derivatives with the derivatives of the natural products.Typically, 3,4-bis(benzyloxy)benzaldehyde (7) on Wittig reaction with triphenyl(11-phenylundecyl)phosphonium bromide (20) and subsequent catalytic hydrogenation of the resultant olefin gave compound (5) in 59percent overall yield.
