95739-48-3

Upstream product

• 92216-29-0 anti-1,4-bis(p-methoxybenzyl)-3-(2'-thiopyridyl)-6-<1''-(hydroxymethyl)-3''-(hydroxypropyl)>-2,5-piperazinedione (major diastereomer) 
• 92098-03-8 syn-1,4-bis(p-methoxybenzyl)-3-(2'-thiopyridyl)-6-<1''-(hydroxymethyl)-3''-(hydroxypropyl)>-2,5-piperazinedione (major diastereomer) 
• 92216-27-8 1,4-dimethyl-3-(2'-thiopyridyl)-6-(2-γ-butyrolactonyl)-2,5-piperazinedione (anti, major diastereomer) 
• 92098-11-8 1,4-bis(p-methoxybenzyl)-3-(2'-thiopyridyl)-6-(2-γ-butyrolactonyl)-2,5-piperazinedione (syn, major diastereomer) 

Downstream Products

• 95694-69-2 Methanesulfonic acid 2-[(1R,4S,5R)-6,8-bis-(4-methoxy-benzyl)-7,9-dioxo-2-oxa-6,8-diaza-bicyclo[3.2.2]non-4-yl]-ethyl ester 

Relevant academic research and scientific papers

Stereocontrolled Total Synthesis of (+/-)- and (+)-Bicyclomycin

The completely regio- and stereocontrolled total synthesis of bicyclomycin (1) is described in 12 chemical steps.A new carbon-carbon bond-forming reaction on 1,4-dibenzyl- and 1,4-bis(p-methoxybenzyl)-3,6-bis(2'-thiopyridyl)-2,5-piperazinediones (10 and 4