95753-26-7Relevant academic research and scientific papers
Synthesis and structure of potential Lewis acid-Lewis base bifunctional catalysts: 2-N,N-Diisopropylaminophenylboronate derivatives
Coghlan, Samuel W.,Giles, Richard L.,Howard, Judith A.K.,Patrick, Leonard G.F.,Probert, Michael R.,Smith, Gillian E.,Whiting, Andrew
, p. 4784 - 4793 (2007/10/03)
Directed ortho-metallation is used to introduce a boron function into N,N-diisopropylbenzamide, resulting in the formation of both borinate and boronate derivatives. N,N-Diisopropylbenzamide ortho-boronate pinacol ester can be reduced with sodium borohydr
BIFUNCTIONAL CATALYSTS
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Page 36-37, (2010/02/10)
Bifunctional Lewis acid - Lewis base catalyst of Formula (I): wherein O is a C2-60 optionally heteroatom containing substituted or unsubstituted hydrocarbon scaffold comprising pendant or integral bifunctional groups LA and LB wherein LA is a pendant or integral boron or silicon Lewis acid group and LB is a pendant or integral phosphorus or nitrogen Lewis base group and its salts, N-fanctionalised derivatives, dimer or oligomer thereof; processes for the preparation thereof; novel compounds and novel intermediates; a composition comprising a catalyst or compound of the invention; a kit comprising one or more catalysts; the use thereof as catalysts in selective transformations, kits therefor and processes for selective transformation reactions catalysed thereby; screening methods to identify catalysts for specific transformations; and kits therefor.
