95762-59-7Relevant academic research and scientific papers
Vaska-Type Iridium Complexes Containing Triisopropylphosphane Ligands
Werner, H.,Hoehn, A.
, p. 1505 - 1509 (2007/10/02)
The complexes trans- (L = CO, py, CH3CN) were prepared from 2 via as intermediate. trans- reacts with LiC2Ph to form trans- which on treatment with HX produces (X = Cl, CF3CO2).The trifluoroacetate ligand is displaced by iodide to give . trans- is obtained from the carbonyl complex and 2-furfurylazide. - Key words: Synthesis, Oxidative Addition Reactions with HX, Octahedral Hydrido(phenylacetylide)iridium(III) Complexes, Vaska Type Iridium Complexes
