95765-18-7

Basic information

• Product Name: [(C₆H₅)4P]⁽¹⁺⁾*[Fe₂Mn(CO)12]^(1-) = [(C₆H₅)4P][Fe₂Mn(CO)12]
• CAS NO: 95765-18-7
• Molecular Weight: 842.153
• Mol File: 95765-18-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(C₆H₅)4P]⁽¹⁺⁾*[Fe₂Mn(CO)12]^(1-) = [(C₆H₅)4P][Fe₂Mn(CO)12](CAS DataBase Reference)
• NIST Chemistry Reference: [(C₆H₅)4P]⁽¹⁺⁾*[Fe₂Mn(CO)12]^(1-) = [(C₆H₅)4P][Fe₂Mn(CO)12](95765-18-7)
• EPA Substance Registry System: [(C₆H₅)4P]⁽¹⁺⁾*[Fe₂Mn(CO)12]^(1-) = [(C₆H₅)4P][Fe₂Mn(CO)12](95765-18-7)

Safety Data

• Hazardous Substances Data: 95765-18-7(Hazardous Substances Data)

Upstream product

• 55029-83-9 [Mn(CO)3(acetonitrile)3]⁽¹⁺⁾ 
• 95765-17-6 {PPh₄}2{(iron)3(CO)11} 
• 37504-44-2 (acetonitrile)pentacarbonylmanganese(I) hexafluorophosphate 

Relevant articles and documents

Synthesis of mixed-metal clusters by facile metal substitution reactions

The anionic clusters [Fe2(CO)8]2-, [Fe4(CO)13]2-, [Ru4(CO)13]2-, and [Fe3W(CO)14]2- react rapidly with 1 equiv of Co2(CO)8 to produce the metal-substituted clusters [FeCo(CO)8]-, [Fe3Co(CO)13]-, [Ru3Co(CO)13]-, and [Fe3Co(CO)13]-, respectively. Similarly [Fe3(CO)11]2- with [Mn(CO)5(CH3CN)]+ yields [Fe2Mn(CO)12]-. Radical spin traps implicate a radical chain reaction with Co2(CO)8. The crystal structure of one of these products [N(PPh3)2][Fe3Co(CO)13] was determined. The metal framework is pseudotetrahedral. Crystal data for [PPN][Fe3Co(CO)13]: triclinic, space group P1, a = 15.255 (5) ?, b = 18.750 (6) ?, c = 9.266 (2) A, α = 79.20 (2)°, β = 86.27 (2)°, γ = 109.48 (2)°, and Z = 2.