957770-73-9Relevant academic research and scientific papers
Mono thiomalonates as thioester enolate equivalents - Enantioselective 1,4-addition reactions to nitroolefins under mild conditions
Clerici, Paolo,Wennemers, Helma
supporting information; experimental part, p. 110 - 113 (2012/01/12)
Mono thiomalonates (MTMs) are introduced as thioester enolate equivalents. Asymmetric organocatalyzed conjugate addition reactions to nitroolefins proceed under mild conditions to afford synthetically useful γ-nitrothioesters with excellent yields and ena
