958264-19-2Relevant academic research and scientific papers
Enantioselective diamination with novel chiral hypervalent iodine catalysts
Mizar, Pushpak,Laverny, Aragorn,El-Sherbini, Mohammad,Farid, Umar,Brown, Michael,Malmedy, Florence,Wirth, Thomas
, p. 9910 - 9913 (2014/08/18)
Vicinal diamines constitute one the most important functional motif in organic chemistry because of its wide occurrence in a variety of biological and pharmaceutical molecules. We report an efficient metal-free, highly stereoselective intramolecular diamination using a novel chiral hypervalent iodine reagent together with its application as an efficient catalyst for the synthesis of diamines.
Exploring the nickel-catalyzed oxidation of alkenes: A diamination by sulfamide transfer
Muniz, Kilian,Streuff, Jan,Hoevelmann, Claas H.,Nunez, Ana
, p. 7125 - 7127 (2008/09/17)
(Chemical Equation Presented) Nickel can oxidize, too! Nickel (II) salts such as nickel chloride and nickel acetylacetonate catalyze the intramolecular diamination of alkenes with urea and guanidine derivatives as well as sulfamides as nitrogen sources. T
