95832-75-0Relevant academic research and scientific papers
Nickel-catalyzed reductive 1,3-diene formation from the cross-coupling of vinyl bromides
Sha, Yunfei,Liu, Jiandong,Wang, Liang,Liang, Demin,Wu, Da,Gong, Hegui
supporting information, p. 4887 - 4890 (2021/06/16)
Facile construction of 1,3-dienes building upon cross-electrophile coupling of two open-chain vinyl halides is disclosed in this work, showing moderate chemoselectivities between the terminal bromoalkenes and internal vinyl bromides. The present method is mild and tolerates a range of functional groups and can be applied to the total synthesis of a tobacco fragrance solanone.
STEREOSPECIFIC SYNTHESIS OF Z- AND E-1-ALKOXY-1,3-BUTADIENES
Luengo, Juan I.,Koreeda, Masato
, p. 4881 - 4884 (2007/10/02)
A stereospecific, highly efficient, generally applicible synthesis of Z- and E-1-alkoxy-1,3-butadienes involving dehydrative decarboxylations of 4,5-unsaturated-2-alkoxy-3-hydroxy-carboxylic acids is described.
New Routes to Substituted 1,3-Dienes, Allylic Alcohols, and α,β-Unsaturated Ketones
Brown, Roger S.,Eyley, Stephen C.,Parsons, Philip J.
, p. 438 - 439 (2007/10/02)
Phenylselenenyl chloride reacts with isoprene giving chloroselenides (1) and (2) which are converted by alkylation and subsequent oxidation into synthetically useful dienes, allylic alcohols, or α,β-unsaturated ketones.
