95837-90-4

Basic information

• Product Name: (2,4,6-Trimethylphenyl-trimethylsilyl)aminodifluorphosphan
• CAS NO: 95837-90-4
• Molecular Weight: 275.354
• Mol File: 95837-90-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2,4,6-Trimethylphenyl-trimethylsilyl)aminodifluorphosphan(CAS DataBase Reference)
• NIST Chemistry Reference: (2,4,6-Trimethylphenyl-trimethylsilyl)aminodifluorphosphan(95837-90-4)
• EPA Substance Registry System: (2,4,6-Trimethylphenyl-trimethylsilyl)aminodifluorphosphan(95837-90-4)

Safety Data

• Hazardous Substances Data: 95837-90-4(Hazardous Substances Data)

Upstream product

• 69563-04-8 N-(trimethylsilyl)-2,4,6-trimethylaniline 

Relevant articles and documents

Bis(trimethyl)-phosphaethene and Tris(trimethylsilyl)silyl-fluorophosphane

Phosphaethenes of the type (Me3Si)2C=P-NRSiMe3 (R = C10H15 (7), CMe3 (8), 2,4,6-Me3C6H2 (10)), LiF, and Me3SiF are obtained in the reaction of the aminodifluorophosphanes (3-5) with the lithium salt of tris(trimethylsilyl)methane (1). 10 is isolated as by-product.The main product is F2PC(SiMe3)3.The lithium salt of tris(trimethylsilyl)silane (2) reacts with 3-6 to give the thermally stable substitution compounds (Me3Si)3Si-PF-NRSiMe3 (11-14).The fluorosilylphosphane Me3Si(CMe3)P-SiFMe-N(SiMe3)2 (15) is formed in the reaction of Me3Si(CMe3)PLi and F2SiMeN(SiMe3)2. - Key words: Phosphaethenes, Silylfluorophosphanes, Fluorosilylphosphane