95838-22-5Relevant academic research and scientific papers
Fungal metabolites. XIII. Isolation and structural elucidation of new peptaibols, trichodecenins-I and -II from Trichoderma viride
Fujita,Wada,Iida,Nishimura,Kanai,Toyama
, p. 489 - 494 (2007/10/02)
Three new groups of peptaibols, trichodecenins, trichorovins and trichocellins, have been isolated from conidia of the fungus, Trichoderma viride. The structures of trichodecenins-I and -II were established by positive-ion fast-atom bombardment, collision-induced dissociation mass spectrometry and two-dimensional NMR spectroscopy. Trichodecenins-I and -II have a (Z)-4-decenoyl group, six amino acid residues and a leucinol moiety in the molecules. Trichodecenin-II was synthesized by the solution-phase method.
NEW SYNTHETIC METHOD OF (Z)-4-ALKENOIC ACIDS USING RING-OPENING REACTION OF (Z)-4-HEXENOLIDE WITH ORGANOCOPPER REAGENT
Fujisawa, Tamotsu,Umezu, Kazuto,Kawashima, Masatoshi
, p. 1795 - 1798 (2007/10/02)
(Z)-4-Hexenolide reacted regioselectively with diorganocuprates to give (Z)-4-alkenoic acids in high yields.Synthetic utility was demonstrated by the convenient synthesis of cis-jasmone.
