95838-80-5

Basic information

• Product Name: 3-Furancarboxylic acid, 5-[[1-(ethoxycarbonyl)-2-oxopropylidene]amino]-4,5-dihydro-2,5-dimeth yl-4-(4-methylphenyl)-, ethyl ester
• CAS NO: 95838-80-5
• Molecular Formula: C22H27NO6
• Molecular Weight: 401.459
• Mol File: 95838-80-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Furancarboxylic acid, 5-[[1-(ethoxycarbonyl)-2-oxopropylidene]amino]-4,5-dihydro-2,5-dimeth yl-4-(4-methylphenyl)-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Furancarboxylic acid, 5-[[1-(ethoxycarbonyl)-2-oxopropylidene]amino]-4,5-dihydro-2,5-dimeth yl-4-(4-methylphenyl)-, ethyl ester(95838-80-5)
• EPA Substance Registry System: 3-Furancarboxylic acid, 5-[[1-(ethoxycarbonyl)-2-oxopropylidene]amino]-4,5-dihydro-2,5-dimeth yl-4-(4-methylphenyl)-, ethyl ester(95838-80-5)

Safety Data

• Hazardous Substances Data: 95838-80-5(Hazardous Substances Data)

Upstream product

• 52287-56-6 1-(p-tolyl)-2-nitropropene 
• 141-97-9 ethyl acetoacetate 

Downstream Products

• 98450-49-8 1-<1-(Ethoxycarbonyl)-2-hydroxy-1-propenyl>-2,5-dimethyl-4-(4-tolyl)-3-pyrrolcarbonsaeure-ethylester 

Relevant articles and documents

Heterocycles from α-Nitroolefins, IX. - N-Substituted 3-Pyrrolecarboxylates from 4,5-Dihydro-5-(methyleneamino)-3-furancarboxylates

Catalytic hydrogenation of 4,5-dihydro-5-(methyleneamino)-3-furancarboxylates 1 yields N-substituted pyrroles 6a-u with enolizable rests at nitrogen and 6v-y with non-enolizable rests at nitrogen.The N-substituted pyrroles 6, 7 react with sodium hypochlorite at the rests standing at nitrogen to yield chlorination products 8.O-Methylated products 9 have been prepared from several N-substituted pyrroles 6 and their enoles 7 with diazomethane; the N-substituted pyrrole 6x yields the C-methylated product 10x.