95851-06-2Relevant academic research and scientific papers
Dithiaphosphagermetannes-1,3,2,4 et dithiaphosphadigermolannes-1,4,5,2,3
Barrau, J.,Amine, M. El,Rima, G.,Satge, J.
, p. 615 - 620 (2007/10/02)
The synthesis of the new germylated and phosphorylated heterocycles 2-anisyl-4,4-dimethyl-2-thio-1,3,2,4-dithiaphosphagermetane, (1), and 5-anisyl-2,2,3,3-tetramethyl-5-thio-1,4,5,2,3-dithiaphosphadigermolane, (2), are described.The decomposition of 1 with formation of (Me2GeS)3 and (AnPS2)n is observed at room temperature.At 200 deg C 2 undergoes thermal fragmentation leading to (Me2GeS)3 and (AnPS)n.These results are explained by two mechanisms of decomposition involving formation of transient species and or , respectively.Exchange reactions between 2 and various metal (MIVB) chlorides are described.With Me2SiCl2 the reaction leads to silathione , probably via transient dithiaphosphasiletane.
THERMOLYSE ET PHOTOLYSE D'HETEROCYCLES A LIAISON Ge-S. MISE EN EVIDENCE DE LA FORMATION DE GERMYLENES ET GERMATHIONES
Barrau, J.,Amine, M. El,Rima, G.,Satge, J.
, p. 323 - 334 (2007/10/02)
The photolysis and thermolysis of 2,3-digerma-1,4-dithianes, 2,3,5-trigerma-1,4-dithiolanes and tetragerma-1,4-dithianes have been studied. 2,2,3,3-Tetramethyl-2,3-digerma-1,4-dithiane (I) decomposes slowly at room temperature by α-elimination to yield di
