95893-77-9Relevant academic research and scientific papers
On the Reduction of 1,3-Thiazinium Salts; Synthesis of 6',6-Bi-1,3-Thiazinyls and 6',6-Bi-1,3-Thiazinylidenes
Ruettinger, H. H.,Spitzner, R.,Schroth, W.,Matschiner, H.,Ziebig, R.
, p. 33 - 40 (2007/10/02)
1,3-Thiazinium perchlorates 1 are linked together in a reaction with the zinc powder or at a cathode forming 6,6'-bi-1,3-thiazinyls 3.This reaction proceeds via radical intermediates 2.Evidence of the existence of the very short-lived radicals is given by means of ring-disk voltammogrammes as well as by electrochemical luminescence excitation.The 6,6'-bi-1,3-thiazinyls 3 undergo the reverse fission at a platinum anode resulting in thiazinium salts 1, whereas the dehydrogenation by chloranile yields the violet 6,6'-bi-1,3-thiazinylidenes 6.
