95895-30-0Relevant academic research and scientific papers
On the Chemistry of Some - and Propellanes
Baumgart, Klaus-Dieter,Harnisch, Hanna,Szeimies-Seebach, Ursula,Szeimies, Guenter
, p. 2883 - 2916 (2007/10/02)
On heating the propellanes 2a and b and the propellanes 3, 4a - c, 5, and 6 were isomerized to the 1,3-dienes 7, 10, 11, 12, and 13.The rates of these rearrangements were strongly enhanced by traces of unknown electrophilic reagents.Addition
SKATTEBOL TYPE REARRANGEMENT VIA α-BROMOTRIMETHYLSTANNYL CYCLOPROPANE THERMOLYSIS. WHAT IS THE MECHANISM?
Warner, Philip M.,Herold, Robert D.
, p. 4897 - 4900 (2007/10/02)
Solution thermolysis of the epimers 5 gave rise to separate sets of products, including, for one, Skattebol-type rearrangement.However, neither epimer produced a free carbene.
