959412-03-4Relevant academic research and scientific papers
Deoxygenative [1,2]-hydride shift rearrangements in nucleoside and sugar chemistry: Analogy with the [1,2]-electron shift in the deoxygenation of ribonucleotides by ribonucleotide reductases
Robins, Morris J.,Nowak, Ireneusz,Wnuk, Stanislaw F.,Hansske, Fritz,Madej, Danuta
, p. 8216 - 8221 (2007)
(Chemical Equation Presented) A variant of the semipinacol rearrangement that was observed in our laboratory has been applied to the synthesis of several furanose and pyranose derivatives. The process consists of an "orchestrated" [1,2]-hydride shift with
