959419-48-8Relevant articles and documents
Meerwein's reagent mediated, significantly enhanced nucleophilic fluorination on alkoxysilanes
Jorapur, Yogesh R.,Shimada, Toyoshi
supporting information; experimental part, p. 1064 - 1068 (2012/06/17)
We developed a new facile method to fluorosilanes from alkoxysilanes using Meerwein's reagent. Our protocol afforded fluorosilanes in excellent yields in various organic solvents including acetonitrile under mild reaction conditions at room temperature. We also proposed a reaction mechanism with the probable silyloxonium intermediates. Georg Thieme Verlag Stuttgart · New York.
Organosilane compound and organosilica obtained therefrom
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Page/Page column 20, (2008/12/07)
Provided is an organosilane compound expressed by any one of the following general formulae (1) to (7): (wherein: Ar represents a phenylene group or the like; R1 represents a hydrogen atom or the like; R2 to R8 each represent a methyl group or the like; n represents an integer in a range from 0 to 2; m represents an integer of 1 or 2; L represents a single bond or the like; X represents a hydrogen atom or the like; and Y represents a hydrogen atom or the like).