Welcome to LookChem.com Sign In|Join Free

CAS

  • or

959627-77-1

[Ti(MeC(2-C5H4N)(CH2N-4-C6H4Me)2)(NMe2)2] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

959627-77-1 Suppliers

Post Buying Request

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier
  • 959627-77-1 Structure

  • Basic information

    1. Product Name: [Ti(MeC(2-C5H4N)(CH2N-4-C6H4Me)2)(NMe2)2]
    2. Synonyms:
    3. CAS NO:959627-77-1
    4. Molecular Formula:
    5. Molecular Weight: 479.504
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 959627-77-1.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [Ti(MeC(2-C5H4N)(CH2N-4-C6H4Me)2)(NMe2)2](CAS DataBase Reference)
    10. NIST Chemistry Reference: [Ti(MeC(2-C5H4N)(CH2N-4-C6H4Me)2)(NMe2)2](959627-77-1)
    11. EPA Substance Registry System: [Ti(MeC(2-C5H4N)(CH2N-4-C6H4Me)2)(NMe2)2](959627-77-1)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 959627-77-1(Hazardous Substances Data)

959627-77-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 959627-77-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 9,5,9,6,2 and 7 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 959627-77:
(8*9)+(7*5)+(6*9)+(5*6)+(4*2)+(3*7)+(2*7)+(1*7)=241
241 % 10 = 1
So 959627-77-1 is a valid CAS Registry Number.

959627-77-1Relevant articles and documents

Imido-alkyne coupling in titanium complexes: New insights into the alkyne hydroamination reaction

Vujkovic, Nadia,Ward, Benjamin D.,Maisse-Francois, Aline,Wadepohl, Hubert,Mountford, Philip,Gade, Lutz H.

, p. 5522 - 5534 (2008/10/09)

Titanium imido complexes [Ti(NR)(N2ArN py)(L)] (N2ArNpy = MeC(2-C 5H4N)(CH2NAr)2, Ar = 4-C 6H4-Me or 3,5-C6H3Me2) have been prepared from the corresponding bis(amide) complexes [Ti(N 2ArNpy)-(NMe2)2]. The reaction chemistry of the imido ligand has been investigated with aryl acetylenes, affording the {2 + 2} cycloaddition products [Ti(N2 ArNpy){κ2-N(tBu)CH=CAr′} ] (Ar′ = Ph and 4-C6H4Me) which represent a catalytic intermediate in the anti-Markovnikov hydroamination of terminal alkynes. Reaction of these azatitanacyclobutene complexes with tert-butylamine completes the catalytic cycle, affording trans-cinnamyl(tert-butyl)amine; conversely, reaction with a second equivalent of alkyne afforded a second insertion product, an azatitanacyclohexadiene [Ti(N2 ArNpy){κ2-N(tBu)CH= C(Ar′)C(Ar′) = CH}], two examples of which have been characterized by X-ray crystallography. Studies into the catalytic hydroamination of phenyl acetylene with tert-butylamine have been performed and indicate that the formation of an azatitanacyclohexadiene complex represents a deactivation pathway in this catalytic reaction.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 959627-77-1