959757-64-3Relevant academic research and scientific papers
Acyclic stereocontrol in the Ireland-Claisen rearrangement of α-branched esters
Qin, Ying-Chuan,Stivala, Craig E.,Zakarian, Armen
, p. 7466 - 7469 (2008/09/18)
(Chemical Equation Presented) To overcome the limitation of the poor diastereoselectivity of the title reaction with α-branched esters, chiral amides were used to generate the enolate intermediates diastereoselectively. The desired rearrangement then took
