95985-05-0Relevant academic research and scientific papers
Asymmetric Hybrid Polyoxometalates: A Platform for Multifunctional Redox-Active Nanomaterials
Hampson, Elizabeth,Cameron, Jamie M.,Amin, Sharad,Kyo, Joungman,Watts, Julie A.,Oshio, Hiroki,Newton, Graham N.
supporting information, p. 18281 - 18285 (2019/11/13)
Access to asymmetrically functionalized polyoxometalates is a grand challenge as it could lead to new molecular nanomaterials with multiple or modular functionality. Now, a simple one-pot synthetic approach to the isolation of an asymmetrically functionalized organic–inorganic hybrid Wells–Dawson polyoxometalate in good yield is presented. The cluster bears two organophosphonate moieties with contrasting physical properties: a chelating metal-binding group, and a long aliphatic chain that facilitates solvent-dependent self-assembly into soft nanostructures. The orthogonal properties of the modular system are effectively demonstrated by controlled assembly of POM-based redox-active nanoparticles. This simple, high-yielding synthetic method is a promising new approach to the preparation of multi-functional hybrid metal oxide clusters, supermolecular systems, and soft-nanomaterials.
Preparation of Robust Metal-Free Magnetic Nanoemulsions Encapsulating Low-Molecular-Weight Nitroxide Radicals and Hydrophobic Drugs Directed Toward MRI-Visible Targeted Delivery
Nagura, Kota,Takemoto, Yusa,Moronaga, Satori,Uchida, Yoshiaki,Shimono, Satoshi,Shiino, Akihiko,Tanigaki, Kenji,Amano, Tsukuru,Yoshino, Fumi,Noda, Yohei,Koizumi, Satoshi,Komatsu, Naoki,Kato, Tatsuhisa,Yamauchi, Jun,Tamura, Rui
supporting information, p. 15713 - 15720 (2017/10/20)
With a view to developing a theranostic nanomedicine for targeted drug delivery systems visible by magnetic resonance (MR) imaging, robust metal-free magnetic nanoemulsions (mean particle size less than 20 nm) consisting of a biocompatible surfactant and
Fluorescent modular boron systems based on NNN- and ONO-tridentate ligands: Self-assembly and cell imaging
Glotzbach, Christoph,Kauscher, Ulrike,Voskuhl, Jens,Kehr, N. Seda,Stuart, Marc C. A.,Froehlich, Roland,Galla, Hans J.,Ravoo, Bart Jan,Nagura, Kazuhiko,Saito, Shohei,Yamaguchi, Shigehiro,Wuerthwein, Ernst-Ulrich
, p. 4410 - 4418 (2013/06/27)
We have synthesized a series of new fluorescent boron systems 1a-c and 2a-d based on nitrogen (NNN) or nitrogen and oxygen (ONO)-containing tridentate ligands. These novel dyes are characterized by high thermal and chemical stability. They show large Stok
The 9-(4-Octadecyloxyphenylxanthen)-9-yl- Group. A new Acid-labile Hydroxyl Protective Group and Its Application in the Preparative Reverse-phase Chromatographic Separation of Oligonucleotides
Kwiatkowski, M.,Chattopadhyaya, J.
, p. 657 - 672 (2007/10/02)
A new 5'-hydroxyl protecting group, 9-(4-octadecyloxyphenylxanthen)-9-yl-(C18Px), and the properties of its ribonucleoside and the ribonucleotide derivatives, have been described.The preparation of a simple reverse-phase silica gel support, whi
