960051-00-7

Basic information

• Product Name: [RuCl₂((C₆H₃OCH₃P(C₆H₅)2)2)(C₅H₄NCH(C₆H₅)NH₂)]
• CAS NO: 960051-00-7
• Molecular Weight: 938.835
• Mol File: 960051-00-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [RuCl₂((C₆H₃OCH₃P(C₆H₅)2)2)(C₅H₄NCH(C₆H₅)NH₂)](CAS DataBase Reference)
• NIST Chemistry Reference: [RuCl₂((C₆H₃OCH₃P(C₆H₅)2)2)(C₅H₄NCH(C₆H₅)NH₂)](960051-00-7)
• EPA Substance Registry System: [RuCl₂((C₆H₃OCH₃P(C₆H₅)2)2)(C₅H₄NCH(C₆H₅)NH₂)](960051-00-7)

Safety Data

• Hazardous Substances Data: 960051-00-7(Hazardous Substances Data)

Upstream product

• 15529-49-4 tris(triphenylphosphine)ruthenium(II) chloride 
• 39930-11-5 1-phenyl-1-(pyridin-2-yl)methanamine 
• 133577-92-1 (R)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) 

Relevant articles and documents

Highly diastereoselective formation of ruthenium complexes for efficient catalytic asymmetric transfer hydrogenation

(Chemical Equation Presented) Jumping Josiphos! Ruthenium cis-dichloro complexes with matched chiral diphosphane and aminopyridine ligands (see structure) are easily obtained by a one-pot reaction of [RuCl 2(PPh3)3] with a Josiphos diphosphane and racemic 1-substituted 1-(pyridin-2-yl)methanamine ligands. These complexes are highly active catalysts for the transfer hydrogenation of ketones, affording turnover frequencies of up to 70000 h-1 at 60°C and ee values up to 99%.