96010-06-9

Basic information

• Product Name: Benzene, 1-bromo-4-(2,2-diphenylcyclopropyl)-
• CAS NO: 96010-06-9
• Molecular Formula: C21H17Br
• Molecular Weight: 349.27
• Mol File: 96010-06-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, 1-bromo-4-(2,2-diphenylcyclopropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-bromo-4-(2,2-diphenylcyclopropyl)-(96010-06-9)
• EPA Substance Registry System: Benzene, 1-bromo-4-(2,2-diphenylcyclopropyl)-(96010-06-9)

Safety Data

• Hazardous Substances Data: 96010-06-9(Hazardous Substances Data)

Upstream product

• 2039-82-9 1-bromo-4-ethenyl-benzene 
• 119-61-9 benzophenone 
• 5350-57-2 benzophenone hydrazone 
• 96010-02-5 benzophenone tosylhydrasone sodium salt 
• 908093-98-1 diazodiphenylmethane 

Downstream Products

• 1251909-11-1 cyclopropyl[bis-(4-(2,2-diphenylcyclopropyl)phenyl)]methanol 
• 1144509-58-9 2-(4-(2,2-diphenylcyclopropyl)phenyl)-2-butanol 
• 1144509-57-8 2-(4-(2,2-diphenylcyclopropyl)phenyl)-2-propanol 

Relevant articles and documents

Hypervalent-iodine(iii) oxidation of hydrazones to diazo compounds and one-pot nickel(ii)-catalyzed cyclopropanation

A one-pot process for the catalytic cyclopropanation of various alkenes with unsubstituted hydrazones is described. Iodosobenzene (Ph = O) was found to be a competent oxidant of hydrazones to diazo compounds. Ni(OH)2 was chosen as an effective and cheap metal catalyst. The cyclopropane products can be generated efficiently (5 min-4 h) in moderate to good yields (42-91%) under mild (80°C) and neat conditions.

Phenyl bridging in ring-substituted cumyloxyl radicals. a product and time-resolved kinetic study

The reactivity of cumyloxyl radicals bearing cyclopropyl and 2,2-diphenylcyclopropyl groups in the para position has been investigated. Depending on radical structure, products deriving from C-C β-scission and/or cyclopropyl ring-opening are observed, sup

THE PHILICITY OF A TRIPLET CARBENE: ADDITIONS OF DIPHENYLCARBENE TO STYRENE SUBSTRATES

Triplet diphenylcarbene adds to ring-substituted styrenes as an ambiphile, reacting more rapidly with electron-rich or electron-poor styrenes than with styrene itself.