96013-80-8

Basic information

• Product Name: Phenol, 2-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-
• CAS NO: 96013-80-8
• Molecular Formula: C13H22O2Si
• Molecular Weight: 238.402
• Mol File: 96013-80-8.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Phenol, 2-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 2-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-(96013-80-8)
• EPA Substance Registry System: Phenol, 2-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-(96013-80-8)

Safety Data

• Hazardous Substances Data: 96013-80-8(Hazardous Substances Data)

Upstream product

• 90-01-7 salicylic alcohol 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 82112-31-0 1-(tert-butyldimethylsilanyloxy)-2-(tert-butyldimethylsilanyloxymethyl)benzene 

Downstream Products

• 161767-40-4 C₁₃H₁₇FO₆ 
• 1433060-70-8 C₁₈H₃₀O₄Si 
• 1433060-77-5 C₁₂H₁₆O₄ 
• 1433060-83-3 C₁₂H₁₅BrO₃ 
• 1420231-35-1 ((1S,4R,4aS,8S,8aS,10S)-8,10-difluoro-7,9-dioxo-1,4,4a,7,8,8a-hexahydro-1,4-ethanonaphthalene-8,10-diyl)bis(methylene)dibenzoate 
• 1204311-30-7 C₂₀H₂₅NO₆Si 

Relevant articles and documents

Stereoselective O-Glycosylations by Pyrylium Salt Organocatalysis**

Despite many years of invention, the field of carbohydrate chemistry remains rather inaccessible to non-specialists, which limits the scientific impact and reach of the discoveries made in the field. Aiming to increase the availability of stereoselective

LYSOPHOSPHATIDYLSERINE DERIVATIVE

PROBLEM TO BE SOLVED: To provide a lysophosphatidylserine derivative or salt thereof. SOLUTION: The present invention provides a lysophosphatidylserine derivative or salt thereof, or a pharmaceutical composition or lysophosphatidylserine receptor function modulator including the compound or salt thereof. SELECTED DRAWING: None COPYRIGHT: (C)2016,JPOandINPIT

An efficient and chemoselective deprotection of tert-butyldimethylsilyl (TBDMS) ethers using tailor-made ionic liquid

Phenolic tert-butyldimethylsilyl (TBDMS) ethers can be deprotected to yield phenols in excellent yield using tailor-made ionic liquid [dihexaEGim][OMs] (dihexaEGim = dihexaethylene glycolic imidazolium salt) as an organic catalyst with alkali-metal fluoride in tert-amyl alcohol. On the contrary, all TBDMS protecting groups can be cleaved cleanly from the bis-TBDMS ether using the same reaction in CH3CN solvent instead of tert-alcohol at 100 °C. This [dihexaEGim][OMs]/tert-amyl alcohol media system allows the highly selective phenolic deprotection reaction of various bis-TBDMS ethers containing both phenolic and aliphatic TBDMS ethers to provide the corresponding phenols in high yield.