960209-12-5

Basic information

• Product Name: N-(2-(1,3-dioxolan-2-yl)ethyl)-4-methylbenzenesulfonamide
• Synonyms: N-(2-(1,3-dioxolan-2-yl)ethyl)-4-methylbenzenesulfonamide
• CAS NO: 960209-12-5
• Molecular Weight: 271.337
• Mol File: 960209-12-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-(2-(1,3-dioxolan-2-yl)ethyl)-4-methylbenzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-(1,3-dioxolan-2-yl)ethyl)-4-methylbenzenesulfonamide(960209-12-5)
• EPA Substance Registry System: N-(2-(1,3-dioxolan-2-yl)ethyl)-4-methylbenzenesulfonamide(960209-12-5)

Safety Data

• Hazardous Substances Data: 960209-12-5(Hazardous Substances Data)

Upstream product

• 5754-35-8 2-[1,3]dioxolan-2-yl-ethylamine 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 1204388-90-8 N-(2-(1,3-dioxolan-2-yl)ethyl)-N-(but-3-enyl)-4-methylbenzenesulfonamide 
• 474759-20-1 4-methyl-N-[(diphenylhydrazono)propyl]-N-(2-propenyl)benzenesulfonamide 
• 474759-05-2 (E/Z)-N-[3-(methoxyimino)propyl]-4-methyl-N-(2-propenyl)benzenesulfonamide 
• 152454-06-3 3-(N-allyltosylamino)propionaldehyde 
• 474759-03-0 N-(2-propenyl)-N-[2-(1,3-dioxolan-2-yl)ethyl]-4-methylbenzenesulfonamide 

Relevant articles and documents

Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings

A combination of organotransition metal catalysis and organocatalysis allows for Tsuji-Trost 5-exo- and 6-exo-cyclizations of aldehydes. This transformation can also be accomplished as a catalytic asymmetric reaction, which affords vinylcyclopentane deriv

Radical cyclization in heterocycle synthesis. Part 13: Sulfanyl radical addition-cyclization of oxime ethers and hydrazones connected with alkenes for synthesis of cyclic β-amino acids

A combination of sulfanyl radical addition-cyclization of the oxime ethers and hydrazones connected with alkenes and subsequent conversion of a phenylsulfanylmethyl group to a carboxyl group provides a novel method for the construction of the cyclic β-amino acids. Upon treatment with thiophenol in the presence of AIBN, the oxime ethers and hydrazones smoothly underwent sulfanyl radical addition-cyclization to give the 2-(phenylsulfanylmethyl)cycloalkylamine. This method was successfully applied to the practical synthesis of 2-aminocyclopentanecarboxylic acid and 4-amino-3-pyrrolidinecarboxylic acid.