960281-00-9Relevant academic research and scientific papers
Synthesis and characterization of β-triketimine cobalt complexes and their behaviour in the polymerization of 1,3-butadiene
Alnajrani, Mohammed N.,Mair, Francis S.
, p. 15727 - 15736 (2014)
Three β-triketimine ligands, (L1: [CH{CMeN(2,4,6-Me3-C6H2)}2C(CMe3N(2-MeO-C6H4)], L2: [CH{CMeN(2,4-Me2-C6H3)}2C(
Rational Design of an Iron-Based Catalyst for Suzuki–Miyaura Cross-Couplings Involving Heteroaromatic Boronic Esters and Tertiary Alkyl Electrophiles
Byers, Jeffery A.,Crockett, Michael P.,Li, Bo,Wong, Alexander S.
supporting information, p. 5392 - 5397 (2020/03/04)
Suzuki–Miyaura cross-coupling reactions between a variety of alkyl halides and unactivated aryl boronic esters using a rationally designed iron-based catalyst supported by β-diketiminate ligands are described. High catalyst activity resulted in a broad substrate scope that included tertiary alkyl halides and heteroaromatic boronic esters. Mechanistic experiments revealed that the iron-based catalyst benefited from the propensity for β-diketiminate ligands to support low-coordinate and highly reducing iron amide intermediates, which are very efficient for effecting the transmetalation step required for the Suzuki–Miyaura cross-coupling reaction.
A comparative study on the reactivity of tris-β-diketiminate ytterbium complexes: Steric effect of β-diketiminato ligands
Jiao, Rui,Xue, Mingqiang,Shen, Xiaodong,Zhang, Yong,Yao, Yingming,Shen, Qi
experimental part, p. 2523 - 2529 (2010/10/01)
A series of tris-β-diketiminate ytterbium complexes with the general formula [YbL3] [L = [N(C6H5)C(Me)] 2CH- LH (1); [N(4-MeC6H 4)C(Me)]2CH-, Ls
