Cas 960383-65-7,(2R,4aR,5S,8S)-2-methyl-4-oxo-5-vinylhexahydro-2H-pyrano[3,2-c]pyridine-6(7H)-carboxylic acid benzyl ester

960383-65-7

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Basic information

Product Name: (2R,4aR,5S,8S)-2-methyl-4-oxo-5-vinylhexahydro-2H-pyrano[3,2-c]pyridine-6(7H)-carboxylic acid benzyl ester
Synonyms: (2R,4aR,5S,8S)-2-methyl-4-oxo-5-vinylhexahydro-2H-pyrano[3,2-c]pyridine-6(7H)-carboxylic acid benzyl ester
CAS NO:960383-65-7
Molecular Formula:
Molecular Weight: 329.396
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: (2R,4aR,5S,8S)-2-methyl-4-oxo-5-vinylhexahydro-2H-pyrano[3,2-c]pyridine-6(7H)-carboxylic acid benzyl ester(CAS DataBase Reference)
NIST Chemistry Reference: (2R,4aR,5S,8S)-2-methyl-4-oxo-5-vinylhexahydro-2H-pyrano[3,2-c]pyridine-6(7H)-carboxylic acid benzyl ester(960383-65-7)
EPA Substance Registry System: (2R,4aR,5S,8S)-2-methyl-4-oxo-5-vinylhexahydro-2H-pyrano[3,2-c]pyridine-6(7H)-carboxylic acid benzyl ester(960383-65-7)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 960383-65-7(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 960383-65-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 9,6,0,3,8 and 3 respectively; the second part has 2 digits, 6 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 960383-65:
(8*9)+(7*6)+(6*0)+(5*3)+(4*8)+(3*3)+(2*6)+(1*5)=187
187 % 10 = 7
So 960383-65-7 is a valid CAS Registry Number.

960383-65-7Upstream product

960383-72-6 (2R,4aS,5S,8aS)-2-methyl-4-oxo-5-vinylhexahydro-2H-pyrano[3,2-c]pyridine-6(7H)-carboxylic acid benzyl ester

960383-65-7Downstream Products

960383-68-0 C₂₉H₄₅NO₆Si

960383-65-7Relevant academic research and scientific papers

Conformational locking through allylic strain as a device for stereocontrol - Total synthesis of grandisine A

Maloney, David J.,Danishefsky, Samuel J.

, p. 7789 - 7792 (2008/09/18)

(Chemical Equation Presented) Controlled fusion: The use of a seco ring D precursor to control both the stereochemistry of a critical cycloaddition with acetaldehyde and the direction of protonation of the resultant silyl enol ether cycloadduct has led to the total synthesis of grandisine A, which shows promising selectivity for binding to the δ-opioid receptor. The D ring is installed in the final stages of the synthesis (see scheme, LA = Lewis acid).

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