960399-15-9Relevant academic research and scientific papers
Asymmetric syntheses of diarylheptanoid natural products (-)-centrolobine and (-)-de-O-methylcentrolobine via hetero-Diels-Alder reaction catalyzed by dirhodium(II) tetrakis[(R)-3-(benzene-fused-phthalimido)-2-piperidinonate]
Washio, Takuya,Yamaguchi, Reika,Abe, Takumi,Nambu, Hisanori,Anada, Masahiro,Hashimoto, Shunichi
, p. 12037 - 12046 (2007)
Catalytic asymmetric syntheses of (-)-centrolobine and (-)-de-O-methylcentrolobine have been achieved, incorporating?a hetero-Diels-Alder (HDA) reaction between 4-aryl-2-silyloxy-1,3-butadienes and phenylpropargyl aldehyde derivatives as a key step. The H
