960403-36-5Relevant academic research and scientific papers
Palladium-catalyzed hydroarylation of 1,3-dienes with boronic esters via reductive formation of π-Allyl palladium intermediates under oxidative conditions
Liao, Longyan,Sigman, Matthew S.
supporting information; experimental part, p. 10209 - 10211 (2010/09/05)
A palladium-catalyzed reductive cross-coupling of 1,3-dienes with boronic esters in which a π-allyl Pd species is generated directly from a 1,3-diene via a Pd-catalyzed aerobic alcohol oxidation is reported. Both the scope of the process and the origin of a highly selective 1,2-addition are discussed.
