96042-52-3

Upstream product

• 14647-23-5 1,2-bis(diphenylphosphino)ethane nickel(II) chloride 
• 68494-09-7 4,5-bis(benzoylthio)-1,3-dithiole-2-one 
• 470664-66-5 3-(5-{4-[5-(2-cyanoethylsulfanyl)-2-thioxo-1,3-dithiol-4-yl-sulfanylmethyl]benzylsulfanyl}-2-thioxo-1,3-dithiol-4-ylsulfanyl)propionitrile 
• 470664-71-2 [Sn(C₆H₄(CH₂S₅C₃)2)(CH₃)2] 
• 352517-72-7 3-(5-{2-[5-(2-cyanoethylsulfanyl)-2-thioxo-1,3-dithiol-4-yl-sulfanyl]ethylsulfanyl}-2-thioxo-1,3-dithiol-4-ylsulfanyl)propionitrile 

Relevant academic research and scientific papers

A new family of sulfur-rich ligands based on the dmit system: Synthesis and metal complexation of 4-4′-covalently bridged bis(2-thioxo-1,3-dithiol-5-thiolato) units

The synthesis of a new series of sulfur-rich ligands is reported. These compounds, which are related to the dmit2- (2-thioxo-1,3-dithiol-4,5-dithiolato) structure, comprise two 2-thioxo-1,3-dithiol-5-thiolato units linked by a bridging unit at the 4-position of the heterocycle via a dithioether spacer unit. Complexation reactions have been carried out on a variety of metal centres; dialkyl tin and gold(I) derivatives have been isolated and fully characterised. The X-ray crystal structure of an octahedral Ni(II) complex, involving two coordinating pyridine molecules, is presented.