960591-78-0Relevant academic research and scientific papers
Carbene adduct of cyclopalladated ferrocenylimine catalyzed α-arylation of ketones with aryl chlorides or bromides
Zhang, Jinli,Yang, Xueqian,Cui, Xiuling,Wu, Yangjie
experimental part, p. 8800 - 8807 (2011/12/02)
Carbene adduct of cyclopalladated ferrocenylimine exhibited highly catalytic activity for the α-arylation of ketones with aryl halides. The corresponding products were obtained in moderate to excellent yields. Such protocol was applied to various ketones and a broad scope of aryl halides including aryl chlorides, bromides as well as unactivated and sterically hindered aryl halides.
A highly practical and general route for α-arylations of ketones using bis-phosphinoferrocene-based palladium catalysts
Grasa, Gabriela A.,Colacot, Thomas J.
, p. 522 - 529 (2013/01/03)
Well-defined, air-stable Pd complexes of bis-phosphinoferrocene family of catalysts have been studied in the arylation of various ketones with aryl chlorides and aryl bromides. Bis(di-tert-butyl)phosphinoferrocene (DtBPF)-based catalysts such as (DtBPF) P
α-arylation of ketones using highly active, air-stable (DtBPF)PdX2 (X = Cl, Br) catalysts
Grasa, Gabriela A.,Colacot, Thomas J.
, p. 5489 - 5492 (2008/09/19)
α-Arylation of various ketones with aryl chlorides and bromides using the well-defined and air-stable (DtBPF)PdX2 (X = Cl, Br) catalysts gave 80-100% yield of the coupled products under relatively mild conditions at low catalyst loadings. The X
