96089-14-4Relevant academic research and scientific papers
Me3(OMe)tBuXPhos: A surrogate ligand for Me4tBuXPhos in palladium-catalyzed C-N and C-O bond-forming reactions
Ueda, Satoshi,Ali, Siraj,Fors, Brett P.,Buchwald, Stephen L.
experimental part, p. 2543 - 2547 (2012/05/20)
A new biarylphosphine ligand, Me3(OMe)tBuXPhos (L3), was designed as a surrogate for Me4tBuXPhos (L1). The Me 3(OMe)tBuXPhos could be prepared in a chromatography-free manner from inexpensive and readily available 2,3,6-trimethylphenol. Comparative studies demonstrated that a catalyst based on Me3(OMe)tBuXPhos displayed the same reactivity as a catalyst based on Me4tBuXPhos for Pd-catalyzed C-N and C-O bond-forming processes.
SELECTIVE MONOBROMINATION OF PHENOLS
Mikhailov, V. A.,Savelova, V. A.,Rodygin, M. Yu.
, p. 1868 - 1870 (2007/10/02)
A method is proposed for the selective monobromination of the hydroxy derivatives of benzene with bis(dimethylacetamide)hydrogen tribromide in aprotic media as brominating agent.
The Nitration of 2,3,4-Tribromo-5,6-dimethylphenol and 3,4-Dibromo-2,5,6-trimethylphenol
Chambers, Mark V.,Hartshorn, Michael P.,Robinson, Ward T.,Vaughan, John
, p. 133 - 144 (2007/10/02)
The nitrations of 2,3,4-tribromo-5,6-dimethylphenol (9) and 3,4-dibromo-2,5,6-trimethylphenol (10) with fuming nitric acid in acetic acid give 2,5,6-trinitrocyclohex-3-enones in addition to 6-hydroxy-2,5-dinitrocyclohex-3-enones.X-ray crystal structure de
