96090-46-9Relevant academic research and scientific papers
2-Pyridyl and 3-pyridylzinc bromides: direct preparation and coupling reaction
Kim, Seung-Hoi,Rieke, Reuben D.
experimental part, p. 3135 - 3146 (2010/06/13)
A facile synthetic approach to the direct preparation of 2-pyridyl and 3-pyridylzinc bromides has been demonstrated using Rieke zinc with 2-bromopyridine and 3-bromopyridine, respectively. A variety of different electrophiles have been coupled with the resulting organozinc reagents to give the corresponding cross-coupling products in moderate to good yields.
A facile synthetic approach to the preparation of 3-pyridyl derivatives: Preparations and coupling reactions of 3-pyridylzinc and its analogues
Kim, Seung-Hoi,Slocum, Tim B.,Rieke, Reuben D.
experimental part, p. 3823 - 3827 (2010/03/04)
A facile synthetic approach to the direct preparation of 3pyridylzinc bromide has been demonstrated using Rieke zinc with 3-bromopyridine in the presence of a catalytic amount of lithium chloride. A variety of different electrophiles have been coupled to give the corresponding cross-coupling products in moderate to good yields. Also, this methodology has been expanded to the preparation of the corresponding organozinc reagents of 3-bromopyridine analogues. Georg Thieme Verlag Stuttgart.
Reactions of Lithium Tributyl Heteroaryl Borates with Allylic Bromides in the Presence of Copper(I) Cyanide
Ishikura, Minoru,Kamada, Machiko,Oda, Izumi,Ohta, Tsukasa,Terashima, Masanao
, p. 377 - 386 (2007/10/02)
The reaction of various lithium tributylheteroarylborates with allylic bromides in the presence of copper(I) cyanide furnished the regioselective allylation at the heteroaryl ring.
Reaction of trialkyl(3-pyridyl)borates with allylic bromides in the presence of copper(I) salts. A new procedure for the preparation of 3-allylpyridine derivatives
Ishikura, Minoru,Kamada, Machiko,Oda, Izumi,Terashima, Masanao
, p. 117 - 120 (2007/10/02)
The reaction of lithium trialkyl(3-pyridyl)borates with allylic bromides in the presence of copper(I) salts was found to give 3-allylpyridine derivatives regioselectively
