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Ni(P(C6H5)3)2(CH2C(C(CH3)2)C(C(CH3)2)CH2) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

96095-76-0

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96095-76-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 96095-76-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,6,0,9 and 5 respectively; the second part has 2 digits, 7 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 96095-76:
(7*9)+(6*6)+(5*0)+(4*9)+(3*5)+(2*7)+(1*6)=170
170 % 10 = 0
So 96095-76-0 is a valid CAS Registry Number.

96095-76-0Downstream Products

96095-76-0Relevant academic research and scientific papers

Study of the Reactions of Substituted Allenes with Tris(triphenylphosphine)nickel(0). An Analysis of the Factors Affecting the Regio- and Stereochemistry of ?-Complex Formation and Coupling To Form Nickelacyclopentane Complexes

Pasto, Daniel J.,Huang, Nai-Zhong,Eigenbrot, Charles W.

, p. 3160 - 3172 (1985)

The reactions of ethylallene (ETA), tert-butylallene (TBA), phenylallene (PHA), cyanoallene (CYA), and methxoyallene (MEA) with tris(triphenylphosphine)nickel(0) have been investigated and compared with the reaction of dimethylallene (DMA) with (TPP)3Ni reported earlier.At low temperatures ( PHA > MEA >> DMA > ETA > TBA.Evidence for a competitive electron-transfer process with CYA is presented.The structures of the intermediate substituted nickelacyclopentane complexes are inferred from the structures of the hydrocarbon products formed in reductive-elimination and hydrogen-migration, reductive-elimination reactions and from the structures of ketonic products formed on reaction with carbon monoxide.Specific ?-?, ?-?, and ?-? modes of coupling in syn and anti conformations of the bis-?-complexes have been identified.The regio- and stereochemistry of formation of the nickelacyclopentane ?-complexes are discussed in terms of steric and electronic (orbital energy and AO coefficients) effects in the rate-determining transition state for ?-complex formation.

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