96097-03-9

Upstream product

• 104172-71-6 Fluor(2,2,6,6-tetramethylpiperidino)<9-(trimethylsilyl)-9H-fluoren-9-yl>boran 

Downstream Products

• 120800-59-1 1-(2''',6'''-diisopropylphenyl)-2,4-bis(2'',2'',6'',6''-tetramethylpiperidino)-1-aza-2,4-diboretidine-spiro-3,9'-fluorene 
• 96097-10-8 (CH₃)4C₅H₆NBC(C₆H₄)2NC₆H₅ 
• 150112-29-1 4',4'-bis(4-chlorophenyl)-2'-(2,2,6,6-tetramethylpiperidino)spiro{fluorene-9,3'-{1,2}thiaboretane} 
• 150112-33-7 4,4-diphenyl-1-methyl-2-(2,2,6,6-tetramethylpiperidino)spiro{1,2-azaboretidine-3,9'-fluorene} 
• 38117-54-3 cyclopentadienyl iron(II) dicarbonyl dimer 
• 150112-32-6 2'-(2,2,6,6-tetramethylpiperidino)spiro{fluorene-9,3'-{1,2}thiaboretane}-4'-thione 
• 150112-28-0 4',4'-diphenyl-2'-(2,2,6,6-tetramethylpiperidino)spiro{fluorene-9,3'-{1,2}thiaboretane} 
• 96097-08-4 4',4'-diphenyl-2'-(2,2,6,6-tetramethylpiperidino)spiro{fluorene-9,3'-{1,2}oxaboretane} 
• 124891-82-3 9-fluorenyliden(tetramethylpiperidino)borane-tricarbonyl-tricyclohexylphosphane iron 
• 136736-63-5 tricarbonyl{η2-9-fluorenylidene(2,2,6,6-tetramethylpiperidino)borane}(methyldiphenylphosphane)iron 
• 136736-65-7 tricarbonyl(dichlorophenylphosphane){η2-9-fluorenylidene(2,2,6,6-tetramethylpiperidino)borane}iron 
• 136736-62-4 tricarbonyl(dimethylphenylphosphane){η2-9-fluorenylidene(2,2,6,6-tetramethylpiperidino)borane}iron 
• 96097-09-5 4'-phenyl-2'-(2,2,6,6-tetramethylpiperidino)spiro{fluorene-9,3'-{1,2}oxaboretane} 

Relevant academic research and scientific papers

Contributions to the Chemistry of Boron, 181. Methyleneboranes as Intermediate of an Olefin Synthesis

Gas phase pyrolysis of fluoro(tetramethylpiperidino)boranes 1 at >= 460 deg C yields (CH3)3SiF, but no methyleneborane 2 could be detected.In solution, (CH3)3SiF is produced at 285 deg C, and in the presence of benzophenone olefins are obtained.The olefin formation is explained by Wittig-type reaction of an intermediate methyleneborane 2 with the ketone.