96097-12-0Relevant academic research and scientific papers
The Phospha-Bora-Wittig Reaction
Borys, Andryj M.,Cowley, Michael J.,Nichol, Gary S.,Rice, Ella F.
supporting information, p. 14065 - 14070 (2021/09/13)
We report the phospha-bora-Wittig reaction for the direct preparation of phosphaalkenes from aldehydes, ketones, esters, or amides. The transient phosphaborene Mes*P═B-NR2 reacts with carbonyl compounds to form 1,2,3-phosphaboraoxetanes, analogues of oxap
Contributions to the Chemistry of Boron, 181. Methyleneboranes as Intermediate of an Olefin Synthesis
Glaser, Bernhard,Noeth, Heinrich
, p. 3856 - 3858 (2007/10/02)
Gas phase pyrolysis of fluoro(tetramethylpiperidino)boranes 1 at >= 460 deg C yields (CH3)3SiF, but no methyleneborane 2 could be detected.In solution, (CH3)3SiF is produced at 285 deg C, and in the presence of benzophenone olefins are obtained.The olefin formation is explained by Wittig-type reaction of an intermediate methyleneborane 2 with the ketone.
