96181-15-6Relevant academic research and scientific papers
Unsymmetrical dimethylhydrazine in phosphorylation reactions
Ryapisova
, p. 1533 - 1535 (2007/10/03)
The reaction of dialkyl hydrogen phosphites with nitrobenzaldehyde dimethylhydrazone leads to formation of compounds having a salt-like structure, while the reaction with hydrazones gives phosphonates. α-Dimethylhydrazinophosphonates were obtained by the
Asymmetric Synthesis of Chiral, Nonracemic Dialkyl α-Hydroxyarylmethyl- and α-, β- and γ-Hydroxyalkylphosphonates from Keto Phosphonates
Meier, Chris,Laux, Wolfgang H. G.,Bats, Jan W.
, p. 1963 - 1980 (2007/10/03)
The enantioselective synthesis of α-hydroxyarylmethylphosphonates 2a-p by the oxazaborolidine-catalyzed reduction of α-keto phosphonates 1a-p using different boranes 4a-c was studied in detail.Moderate to good enantioselectivities are found (up to 80perce
ASYMMERIC CATALYSIS IN CARBON-PHOSPHORUS BOND FORMATION
Wynberg, Hans,Smaardijk, Ab A.
, p. 5899 - 5900 (2007/10/02)
o-Nitrobenzaldehyde reacts smoothly with dialkylphosphonates in the presence of catalytic quantities of cinchona alkaloids (e.g.quinine) to produce the α-hydroxy phosphonate esters in excellent chemical yields, with excellent enantiomeric enrichment.
