96185-30-7Relevant academic research and scientific papers
Two new catalysts for the dehydrogenative coupling reaction of carboxylic acids with silanes - Convenient methods for an atom-economical preparation of silyl esters
Liu, Guo-Bin,Zhao, Hong-Yun,Thiemann, Thies
, p. 2717 - 2727 (2008/02/12)
Tris(triphenylphosphine)cuprous chloride [Cu(PPh3)3Cl] has been found to be an efficient catalyst for the dehydrosilylation of carboxylic acids with silanes. In the presence of 4 mol% Cu(PPh3)3Cl, dehydrosilylation reactions in acetonitrile afforded the corresponding silyl esters at 80°C in good yields. It was noted that triphenylphosphine itself also functions as an adequate catalyst for the reaction. Copyright Taylor & Francis Group, LLC.
Triphenylphosphine-catalyzed dehydrogenative coupling reaction of carboxylic acids with silanes - A convenient method for the preparation of silyl esters
Liu, Guo-Bin,Zhao, Hong-Yun,Thiemann, Thies
, p. 807 - 811 (2008/03/27)
Triphenylphosphine has been found to be an efficient catalyst for the dehydrosilylation of carboxylic acids with silanes. In the presence of 4 mol % of triphenylphosphine (PPh3), dehydrosilylation reactions in DMF afforded the corresponding silyl esters at 120 °C in good yield.
1,8-DIAZABICYCLOUNDEC-7-ENE(DBU): AN EFFECTIVE BASE FOR THE INTRODUCTION OF t-BUTYLDIMETHYLSILYL GROUP IN ORGANIC COMPOUNDS.
Aizpurua, Jesus M.,Palomo, Claudio
, p. 475 - 476 (2007/10/02)
Reaction of alcohols, thiols, amines, carboxylic acids, phenols, hydroquinones, ketoesters and amides with equimolecular amounts of t-butyldimethylchlorosilane and DBU, even in solvents other than dimethylformamide affords the corresponding t-butyldimethy
