96213-49-9

Upstream product

• 109-97-7 pyrrole 
• 12103-40-1 bis(triphenylphosphine)-rhenium heptahydride 
• 558-37-2 tert-butylethylene 
• 16853-85-3 lithium aluminium tetrahydride 
• 96227-72-4 C₄H₄NRe{(C₆H₅)3P}2HI 

Downstream Products

• 96213-50-2 {(C₆H₅)3P}2ReH₂(NC₄H₃(CH₃)) 
• 96213-51-3 {(C₆H₅)3P}2ReH₂(NC₄H₃(CH₂CH₂CH₂CH₃)) 
• 96227-70-2 ReH₂(P(C₆H₅)3)2(C₄H₄NCH₃)⁽¹⁺⁾ 
• 96227-72-4 C₄H₄NRe{(C₆H₅)3P}2HI 

Relevant academic research and scientific papers

1,2- AND 1,2,5-SUBSTITUTED PYRROLES FROM AN (γ5-pyrrolyl)-TRANSITION METAL COMPLEX

Reaction of (L)(Ph3P)2ReH2 (L = η5-pyrrolyl) with acyl chlorides leads directly to N-acylpyrroles in high yields; with methyl triflate cations (L')(Ph3P)2ReH2(1+) (l = η5-N-methylpyrrole) are formed, which release N-methylpyrroles by

The regioselective elaboration of η-pyrrolyl ligands in (η-pyrrolyl)bis(triphenylphosphine)rhenium complexes: a way to 2,5-diphenylpyrrole and some of its N-derivatives

The η-pyrrolyl complexe (η-C4H4N)(Ph3P)2ReH2 (I) was prepared from (Ph3P)2ReH7, 3,3-dimethyl-1-butene and pyrrole, and treated with I2-K2CO3 to give (η-C4H4N)(Ph3P)2ReHI (2).This was treatede with PhLi to give (η-2-PhC4H3N)(Ph3P)2ReH2 (3) in high yield.Re