96226-11-8

Basic information

• Product Name: Benzenemethanol, a-(2,2-dimethylpropyl)-a-methyl-
• CAS NO: 96226-11-8
• Molecular Formula: C13H20O
• Molecular Weight: 192.301
• Mol File: 96226-11-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-(2,2-dimethylpropyl)-a-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-(2,2-dimethylpropyl)-a-methyl-(96226-11-8)
• EPA Substance Registry System: Benzenemethanol, a-(2,2-dimethylpropyl)-a-methyl-(96226-11-8)

Safety Data

• Hazardous Substances Data: 96226-11-8(Hazardous Substances Data)

Upstream product

• 590-50-1 4,4-dimethyl-pentan-2-one 
• 591-51-5 phenyllithium 
• 84379-72-6 1,3-dioxoisoindolin-2-yl 3,3-dimethylbutanoate 
• 98-83-9 isopropenylbenzene 
• 100-58-3 phenylmagnesium bromide 
• 677-22-5 tert-butylmagnesium chloride 

Downstream Products

• 223128-57-2 (1-chloro-1,3,3-trimethyl-butyl)-benzene 

Relevant articles and documents

Air-assisted addition of grignard reagents to olefins. A simple protocol for a three-component coupling process yielding alcohols

Silylmethyl, tertiary-alkyl, alkenyl, and aryl Grignard reagents underwent intermolecular addition to olefins, such as styrenes, conjugated dienes, and enynes under an air atmosphere to give homologated alcohols. For example, (trimethylsilyl)methylmagnesi

Multicomponent Oxyalkylation of Styrenes Enabled by Hydrogen-Bond-Assisted Photoinduced Electron Transfer

Herein, we disclose a strategy for the activation of N-(acyloxy)phthalimides towards photoinduced electron transfer through hydrogen bonding. This activation mode enables efficient access to C(sp3)-centered radicals upon decarboxylation from bench-stable and readily available substrates. Moreover, we demonstrate that the formed alkyl radicals can be successfully employed in a novel redox-neutral method for constructing sp3?sp3 bonds across styrene moieties that gives straightforward access to complex alcohol and ether scaffolds.