96239-07-5Relevant academic research and scientific papers
PROTECTION DES PHENOLS PAR LE GROUPEMENT AZIDOMETHYLENE APPLICATION A LA SYNTHESE DE PHENOLS INSTABLES
Loubinoux, Bernard,Tabbache, Samir,Gerardin, Philippe,Miazimbakana, Joseph
, p. 6055 - 6064 (2007/10/02)
Phenols are protected by the azidomethylene group in basic, nucleophilic, oxidative, weakly reductive and weakly acidic media.This group is obtained by the reaction of sodium azide with aryloxymethyl chlorides.Its utility lies in the ease with which it can be removed under very mild conditions which allows the synthesis of very unstable phenolic compounds.
Preparation d'aryloxymethyl-1 triazoles-1,2,3
Loubinoux, Bernard,Colin, Jean-Luc,Tabbache, Samir
, p. 1669 - 1672 (2007/10/02)
The preparation of 1-aryloxymethyl-1,2,3-triazoles, potential biologically active compounds particularly in the pesticide field, is described.The action of sodium azide on aryloxymethyl halides gave aryloxymethyl azides.The cycloaddition reactions of azid
