96239-87-1Relevant academic research and scientific papers
DIASTEREOTOPIC SELECTIVITY AT PROCHIRAL CARBON CENTERS. A STEREODIVERGENT SYNTHESIS OF THE TALAROMYCINS.
Schreiber, Stuart L.,Sommer, Toby J.,Satake, Kunio
, p. 17 - 20 (1985)
The transformation of the acyclic precursor previously employed in the synthesis of talaromycin B to the stereoisomeric avian toxin talaromycin A is described.Diastereotopic selectivity at prochiral carbon centers in an acetonide migration and in a subseq
