96249-39-7Relevant academic research and scientific papers
Photochemistry of Phenyl Azide: The Role of Singlet and Triplet Phenylnitrene as Transient Intermediates
Leyva, Elisa,Platz, Matthew S.,Persy, Gabriele,Wirz, Jakob
, p. 3783 - 3790 (1986)
The sequence of transient intermediates formed by the photolysis of phenyl azide (1) was determined by a combination of techniques including absorption, emission, and EPR spectroscopies as well as quantitative product analyses of irradiated glassy solutio
2,6-DIMETHYLPHENYLNITRENE IN LOW-TEMPERATURE MATRICES
Dunkin, Ian R.,Donnelly, Thomas,Lockhart, Thomas S.
, p. 359 - 362 (2007/10/02)
Photolysis of 2,6-dimethylphenyl azide on N2 matrices at 12K gives 2,6-dimethylphenylnitrene; in presence of CO, the nitrene forms the corresponding isocyanate, while on shorter wavelength irradiation, it undergoes an inefficient rearrangement to an azacycloheptatetraene.
