96251-89-7Relevant academic research and scientific papers
REDUCTION D'ACETALS γ-BROMO α-ACETYLENIQUES PAR LES SELS CHROMEUX : ACCES AUX ACETALS ET ALDEHYDES α-ALLENIQUES.
Ledoussal, B.,Gorgues, A.,Coq, A. Le
, p. 51 - 52 (2007/10/02)
Reduction of γ-bromo α-acetylenic acetals 1 with chromous ions (THF + HMPA) in the presence of AcOH affords α-allenic acetals 2 whose careful hydrolysis yields the corresponding aldehydes 3.A new access to the dried bean beetle pheromone (racemic), via a
