96282-38-1Relevant academic research and scientific papers
A new electrochemical procedure for preparing 2,4,6-triphenylselenopyran from 1,5-diketones under conditions of acid catalysis
Dmitrienko,Popova
, p. 448 - 451 (2008/09/20)
A new electrochemical procedure was developed for preparing 2,4,6-triphenylselenopyran from 1,5-diketones under conditions of acid catalysis at oxidative electrochemical activation of hydrogen selenide in the presence of a one-electron oxidizing agent in a nonaqueous solution. The electrolysis products were analyzed by gas chromatography with a mass-selective detector.
REACTIONS OF 1,5-DIKETONES WITH HYDROGEN SELENIDE IN THE PRESENCE OF TRIFLUOROACETIC ACID
Kharchenko, V. G.,Drevko, B. I.
, p. 1345 - 1348 (2007/10/02)
Two competing pathways were found in the transformations of 1,5-diketones and the 4H-selenopyrans formed from these diketones upon reaction with CF3CO2H in the presence of hydrogen selenide entailing disproportionation and the electrophilic addition of hydrogen selenide.
